Spoiler about Requiem Sentinels...

Why are they friendly yet Promeathean AIs are hostile?
Aren’t they both Forerunner creations?
Or is it that Sentinels are in command of Librarian?

I would assume that they are either in the command of the librarian or that they recognise Chief as a reclaimer. More likely the former as they led him to the Librarian in the fifth mission